http://www.sendmail.org/ — Offers a thorough technical breakdown of Sendmail features, documentation and configuration examples.
http://www.sendmail.com/ — Contains news, interviews and articles concerning Sendmail, including an expanded view of the many options available.
http://www.postfix.org/ — The Postfix project home page contains a wealth of information about Postfix. The mailing list is a particularly good place to look for information.
http://www.uwasa.fi/~ts/info/proctips.html — Contains dozens of tips that make using Procmail much easier. Includes instructions on how to test .procmailrc files and use Procmail scoring to decide if a particular action should be taken.